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Q.

An aqueous solution of compound A gives white precipitate with 2 M HCI. The precipitate becomes black on addition of aqueous NH3 due to formation of B.B dissolves in aquaregia A and B are:

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a

Hg2+ and HgCl2

b

Hg22+ and Hg2Cl2

c

Hg2+ and HgNH2Cl+Hg

d

Hg22+ and HgNH2Cl+Hg

answer is D.

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Detailed Solution

Hg22+ (A) HClHg2Cl2 (White ppt.)   aq. NH3 Hg+Hg2NH2ClBlack(B)

Since Hg gives white precipitate when treated with HCl. Then white ppt. turn into black by dissolving in aq.NH3. The correct option is D.

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