Q.

An aqueous solution of glucose boils at 100.01oC. The molal elevation constant for water is 0.5 K mol-1 kg. The number of molecules of glucose in the solution containing 100 g of water is

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a

12.046×1020

b

6.023×1023

c

6.023×1022

d

12.046×1023

answer is C.

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Detailed Solution

  ΔTb=Kb×Cm

Or Cm=0.010.5=0.02 mole kg1 solvent

 number of moles in 100 g water =0.02×1001000

                                                                          = 0.002 moles of glucose 

                                                                           =0.002×6.023×1023 molecules of glucose

                                                                          =2×6.023×1020 glucose moles = 12.046×1020

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