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An azeotropic mixture of water(b.pt=100⁰c) and HCl (b.pt = 85⁰C) boils at 108.50c. When this mixture is distilled, it is possible to obtain

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Pure water

Neither HCl nor H₂O in pure state

Pure HCl

Both HCl & water

answer is D.

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Detailed Solution

BP of H₂O = 100^oc

BP of HCl = 85^oc

BP of (HCl+H₂O) azeotrope = 108.5^oc

It is a maximum boiling azeotrope

It is not possible to separate the components of an azeotrope

Because both the components boil at same temperature

An azeotrope is a constant boiling mix.

$\therefore$ neither HCl nor H₂O can be obtained in pure state by fractional distillation

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