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Q.

An electrical double layer is formed in the following in which mobile phase is positively charged

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a

SnO2 in HCl

b

Agl in KI

c

SnO2 in NaOH

d

Agl in AgNO3

answer is A, D.

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Detailed Solution

(1) AgI+AgNO3[AgI]Ag+Fixed partNO3Mobile part

(2) AgI+KI[AgI]IFixed part  K+Mobile part

(3) SnO2+2NaOHNa2SnO3+H2O

SnO2+Na2SnO3SnO2SnO32Fixed part  2Na+Mobile part

(4) SnO2+4HClSnCl4+2H2O

SnO2+SnCl4SnO2Sn4+Fixed part  4ClMobile part

 In NaOH1SnO2 is converted to SnO32 which is adsorbed on SnO2

 In HCl,SnO2 is converted to Sn4+ which is adsorbed on SnO2

Fixed part of the electrical double layer in sol while mobile part remains in medium.

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