An electrochemical cell can behave like an electrolytic cell when

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$E_{cell} = 0$

$E_{cell} > E_{ext}$

$E_{ext} > E_{cell}$

$E_{cell} = E_{ext}$

answer is C.

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Detailed Solution

When $E_{ext} > E_{cell,}$ the cell starts behaving like an electrolytic cell. The external source of voltage is used to bring about a chemical reaction.

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