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Q.

An electron from various excited states of hydrogen atom emit radiation to come to the ground state λn, λg be the de Broglie wavelength of the electron the nth  state and the ground state respectively. Let n  be the wavelength of the emitted photon in the transition from the nth  state to the ground state. For ( A, B are constants

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a

Λn2λ

b

ΛnA+Bλn2

c

ΛnA+Bλn

d

Λn2A+BλN2

answer is A.

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Detailed Solution

Momentum of electron in different states

        pn=hλn, pg=hλg

Kinetic energy, K=p22m=h22mλ2

Total energy in an orbit of hydrogen atom,

E=-K=-h22mλ2 En-Eg=h22m1λg2-1λn2

      h22mλm2-λg2λg2λn2=hcΛn  Λn=2mchλg2λn2λm2-λg2  Λn=2mcλg2h1-λg2λn2-1=2mcλg2h1+λg2λm2                    λgλn  Λn=2mcλg2h+2mcλg4h1λm2=A+Bλm2

 where A and B are A=2mcλg2h,B=2mcλg4h

Hence, the correct answer is (A).

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