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Q.

An element A (Atomic weight = 120) having be, structure has unit cell edge length 400 pm. Identify the correct option(s). (Given:NA=6×1023)

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a

The density of solid element. is 6.25gm/cm3.

b

There are 6×1022 unit cells in 24 gm of the solid element.

c

The atomic radius is about 1.732A

d

In 25 gm of solid element, the volume occupied by atoms is nearly 2.72cm3 only

answer is A, B, C, D.

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Detailed Solution

Density,

d=Z×Ma3×NA

d=2×12064×1024×6×1023d=406.4=10.16g/cm3=6.25g/cm3

 Number of moles = mass  molar mass 

Number of unit cells,

n=12×10222 n=6×1022

It is known that,

3a=4r

r=34×400

r=1.732×100pm=1.732

Also,

 Volume of the unit cell = mass  density =256.25

Voccupied =0.68×256.25=2.72cm3

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