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Q.

An element A in a compound ABD has oxidation number An-. It is oxidised by Cr2O72- in acid medium. In the experiment 1.68  × 10-3 moles of  K2Cr2O7  was used for 3.26  × 10-3 moles of ABD. The new oxidation number of A after oxidation is

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a

+n

b

n-3

c

3-n

d

3

answer is B.

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Detailed Solution

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Cr changes its oxidation state from +6 to +3 in acidic medium on oxidizing a compound. 


So, the net change in oxidation per molecule of K2​Cr2​O7 is +6 (2 Cr atoms per molecule). 


As 1 equivalent of K2​Cr2​O7 oxidizes two equivalents of ABD, then each A atom changes its oxidation state by 3.

So, the new oxidation state is 3−n.

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