Q.

An element crystallizes as body centred cubic lattice. Its density is 7.12 g cm–3 and the length of the side of the unit cell is 2.88 Ao . Calculate the number of atoms present in 288 g of an element is 3.386×104×x then find the x.

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answer is 6.

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Detailed Solution

Density=7.12 gcm−3

 NA​=6.022×1023

 z = 2 (B.C.C lattice)

 a = side length = 2.88A0=2.88×10−8cm

 Putting the values of all this in above equation,

7.12=2×M6.022x1023x(2.88x10-8)3

After solving, we get 

 M = 51.2 g

 Number of mole (n) =  given massmolar mass

 n=28851.2=5.63

 Number of atoms = n ×NA​

 Number of atoms = 5.63×6.02×1023

 Number of atoms = 3.39×1024

 Hence, number of atoms present is 288 g of the element = 3.39×104x6

Then x=6

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