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Q.

An element R (Atomic weight = 120) having bcc structure has unit cell edge length 400 pm. Identify the INCORRECT Option(s) (Given: N A =6× 10 23  )


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a

The density of solid element is 6.25g/c m 3  

b

There are 6× 10 22   unit cells in 24g of R

c

The atomic radius of R is 1.732 A 0  .

d

In 25 g of solid R, the volume occupied by atoms is 2.96 c m 3  . 

answer is D.

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Detailed Solution

detailed_solution_thumbnail
A) 4r= 3 ar= 3 ×100pm  
b) d= 2×120 6× 10 23 × 4× 10 8 3 g/ cm 3 =6.25g/ cm 3  
C) 0.1 mol unit cell-2 mol R
0.1 mol unit cell -0.2 mol R
d)  25g is 25 6.25 cm 3 =4 cm 3  
  • volume occupied by atoms =0.68×4 cm 3  

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