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Q.

An endothermic reaction has a positive value for ΔS∘ • Which of the following is true about the equilibrium. constant for this reaction?

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a

It may be greater than 1 only at high temperatures.

b

It is greater than 1 at all temperatures.

c

It may be greater than 1 only at low temperatures.

d

It is less than 1 at all temperatures,

answer is B.

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Detailed Solution

Here, we have,

ΔG∘=ΔH∘−TΔS∘

ΔS∘>0 At high T,ΔG∘<0⇒K>1

 

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