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Q.

An endothermic reaction is nonspontaneous at freezing point of water and becomes feasible at its boiling point, then:

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a

ΔH=+ve,ΔS=-ve

b

 Both ΔH and ΔS are -ve 

c

 Both ΔH and ΔS are +ve

d

ΔH=-ve,ΔS=+ve

answer is B.

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Detailed Solution

ΔG=ΔH-TΔS At low T, ∆H and ∆S  are positive but ∆G  is also positive at high temperature T∆S>∆H and ∆G=-νe 

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