Q.

An equilibrium is established SO2,O2 and SO3 as SO2(g)+12O2(g)SO3(g) starting with 2 moles SO2 and 1.5 moles O2 in 5 liter flask. The equilibrium mixture required 0.4  moles of KMnO4 in acidic medium. The value of KC is :

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a

5

b

5

c

25

d

0.2

answer is B.

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Detailed Solution

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t=0  2    1.5

t=teq 15 15 15

SO2+KMnO4Mn2++SO42

nf=2 nf=5

2×nSO2=5×0.4

nSO2=1

KC=151515=5

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