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Q.

An equilibrium mixture of NO2(g) and N2O4(g) is present in a closed container at 300 K With pressures 0.4 atm and 0.2 atm respectively. On doubling the volume of container > the presaure of NO2(g)  at new equilibrium at 300 K will be:

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a

0.2 atm

b

0.35 atm

c

0.19 atm

d

0.25 atm

answer is D.

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Detailed Solution

The reaction takes place as,

N2O42NO2 KP1=(0.4)20.2=0.8

 Old eq. 0.20.4 New eq. 0.1x0.2+2x

(0.2+2x)2(0.1x)=0.8

PNO2=0.25atm

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