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An equilibrium ${SO}_{2_{(g)}} + {Cl}_{2_{(g)}} ⇌ {SO}_{2} {Cl}_{2_{(g)}}$ has been established in a closed container at T K. If additional amount of $S O_{2}$ has been introduced into same container the wrong relation regarding their old and new equilibrium concentrations is ___?

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${[{SO}_{2} {Cl}_{2}]}_{old} < {[{SO}_{2} {Cl}_{2}]}_{new}$

${[C l_{2}]}_{old} > {[C l_{2}]}_{new}$

${[S O_{2}]}_{old} < {[S O_{2}]}_{new}$

${[S O_{2}]}_{old} > {[S O_{2}]}_{new}$

answer is D.

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Detailed Solution

Due to addition of $S O_{2_{(g})}$ ,the old equilibrium get disturbed and forward reaction occurs. But final number of moles of $S O_{2_{2 (g)}}$ at new equilibrium are greater than number of moles of $S O_{2_{2 (g)}}$ at old equilibrium.

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