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Q.

An ideal gas is taken from the state A (pressure P, volume V) to the state B (pressure P/2, volume 2V along a straight line path in the P-V diagram. Select the correct statement(s) from the following:

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a

In the T-V diagram, the path AB becomes a part of parabola.

b

In going from A to B, the temperature T of the gas first increases to a maximum value and then decreases.

c

In the P-T diagram, the path AB becomes a part of hyperbola.

d

The work done by the gas in process AB is greater than the work that would be done if the system were taken from A to B along the isotherm 

answer is A, B, D.

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Detailed Solution

i. Work done = area under the curve,

   W1=P+P2(2VV)=32PV

Work done under isothermal process,

         W2=RT×2.3026log2VV               =0.693RT=0.693PV W1>W2, i.e., option (a) is correct. 

ii. Let P0 and V0 be the intercepts on the P and V axes. Now the equation of straight line would be

         P=P0V0×V+P0( y=mx+c)

Further   PV=RT  or  P=RTV

(This represents parabola, so option (b) is also correct.)

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