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Q.

An ideal gas (relative permittivity  r=1) having f degrees of freedom is kept inside a thermally insulated vessel, the vessel has two large pistons each with charge +Q and -Q. Assume charges are uniformly distributed. Pistons can move without friction inside the vessel. At an instant, the charge of pistons is increased k times with the help of an external agent. Then which of the following statement(s) is/are correct.

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a

The ratio of final to initial temperature of gas in equilibrium is  K2+f2+f

b

Work done by the agent in the process is  (K21)nRT1 where  T1  is initial temperature.

c

Work done by the agent in the process is (K21)Q2L12A0  where  L1 is initial separation between pistons                                       

d

The ratio of final to initial temperature of gas in equilibrium is 2K2+f2+f

answer is B, C, D.

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Detailed Solution

Stage 1

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P1AL1=nRT1

Q22A0=P1A=nRT1L1 (Force Balancing)

Stage 2 
Charge is suddenly changed
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System is not in equilibrium 
Stage 3
 

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Finally system in equilibrium

P2AL2=nRT2              K2Q22A0=nRT2L2
Energy of the system is conserved between stages 2 and 3
120E22AL1+f2nRT1=120E22AL2+f2nRT2
 On solving all the above equation
T2T1=2K2+f2+f           Wext=(K21)Q2L12A0=(K21)nRT1

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