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Q.

An ideal gas undergoes a cyclic  process  as shown in fig
   Question Image  

UBC=5kJmol1,qAB=2kJmol1
WAB=5kJmol1,WCA=3kJmol1
Heat absorbed by the system during process CA is ;

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a

18kJmol1

b

+5kJmol1

c

5kJmol1

d

18kJmol1

answer is B.

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Detailed Solution

UAB=qAB+WAB=2+(5)=3kJ/mol

UBC=5kJ/mol

For cyclic process,  U=0
UAB+UBC+UCA=0
UCA=UABUBC
UCA=(3)(5)=8kJ/molπ6
UCA=qCA+WCA
8=qCA+3qCA=+5kJ/mol
Heat absorbed has positive sign

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