Q.

An ideal gas undergoes a process in which  PV2=constant, where V is the volume occupied by the gas initially at pressure P. At the end of the process, rms speed of gas molecules has became  21/2 times of its initial value. Find the value of  Cv so that energy transferred by the heat to the gas is ‘2’ times of the initial energy.

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a

5R3

b

3R5

c

3R

d

R3

answer is D.

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Detailed Solution

PV2=Constant

Molar heat capacity in the process
PVx=Constant , is 
 C=Rr1+R(1x)=Cv+R1(2)=Cv+R3
At the end of the process  Vrms is  21/2 times. Temperature has become ‘2’ times.  (VrmsT1/2)
ΔQ=nCΔT=nCT(a1)=n[Cv+R3]2T-T 
But given  ΔQ=2Ui

ΔQ=2nCVT
Or  nCV+R3(T)=2nCvT

Or  CV=R3

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