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Q.

An impure sample of sodium oxalate (Na2C2O4) weighing 0.20 g is dissolved in aqueous solution of H2SO4 and solution is titrated at 70° C, requiring 45 mL of 0.02 M KMnO4 Solution. The end point is over run, and back titration in carried out with 10 mL of 0.1 M oxalic acid solution. Find the % purity of Na2C2O4 in sample. (Na=23, C=12)

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answer is 83.75.

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Detailed Solution

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Meq. of Na2C2O4 = Meq. of KMnO4 reacted

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