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Q.

An industrial method of preparation of methanol is

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a

by reacting formaldehyde with aqueous sodium hydroxide solution

b

by reacting methane with steam at 900 °C with a nickel catalyst

c

catalytic reduction of carbon monoxide in presence of ZnOCr2O3.

d

by reducing formaldehyde with lithium aluminium hydride

answer is A.

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Detailed Solution

The catalytic reduction of carbon monoxide is a step in the industrial process of making methanol. Water gas is employed for this purpose. An equimolar combination of water and gas CO and  H2. a combination of chromium oxide and zinc oxide ZnOCr2O3.produces methanol from water gas CH3OH. The reaction is occurring at 573 K. CO+2H2ZnO2Cr2OCH3OH.

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