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Q.

An inorganic compound 'A' shows the following reactions
i) It is white solid, exists as dimer and fumes in wet air
ii) It sublimes at 1800C and forms monomer if heated to 4000C
iii) Its aqueous solution turns blue litmus to red and gives a white precipitate with AgNO3 solution which is soluble in NH4OH
iv) Addition of NH4OH and NaOH separately to the soltion of 'A' gives a gelatinous precipitate which in however soluble in excess of NaOH.
The compound 'A' is

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a

Al(OH)3

b

Al2Cl6

c

Al2O3

d

Al2(SO4)3

answer is B.

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Detailed Solution

I) 2AlCl3Monomerwhite solidAl2Cl6Dimer AlCl3+3H2OAlOH3+3HClDense fumes

II),A{l_2}C{l_6}_{_{(S)}}xrightarrow[{Sublim ation}]{{{{180}^0}c}}A{l_2}C{l_6}_{_{(g)}}xrightarrow[{{{400}^0}c}]{}mathop {2AlC{l_3}}limits_{Monomer}
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