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Q.

An inorganic white crystalline compound (A) has a rock salt structure. (A) on reaction with cone. H2SO4 and MnO2 , evolves a pungent smelling, greenish-yellow gas (B). Compound (A) gives white ppt. of (C) with AgNO3 solution. Compounds (A), (B) and (C) will be respectively:

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a

NaBr,Br2,NaBr

b

NaCl,Cl2,Ag2SO4

c

Na2CO3,CO2,Ag2CO3

d

NaCl,Cl2,AgCl

answer is A.

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Detailed Solution

NaC1, a white crystalline solid with a rock salt crystal structure, is Compound A. B is Cl2, a gas with a strong scent and a greenish hue.  AgNO3 and NaC1 interact, resulting in the formation of a white, milky precipitate of NaC1.

2NaCl+2H2SO4+MnO2Na2SO4+MnSO4+2H2O+Cl2AgNO3+NaClNaNO3+AgCl

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