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Q.

An ionic compound AB crystallises in b.c.c lattice. If its unit cell edge length is 412 pm and radius of B- is 181 pm, the radius of A+ is : 

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a

351.6pm

b

200pm

c

100pm.

d

175.8pm

answer is B.

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Detailed Solution

For b.c.c lattice,

2rA++rB=a3

             rA++rB=a32=412×1.7322=356.8pm          rA++181pm=356.8pm                     rA+=356.8pm181pm=175.8pm.

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