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Q.

An ionic solid A+B crystallizes as a body centred cubic structure. The distance between cation and anion in the lattice is 338 pm. Calculate the edge length of the unit cell (in pm).

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answer is 390.3.

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Detailed Solution

In a body centred cubic unit cell, the distance
between the cation and anion (r++r) is related
to the edge length (a) by
r++r3×a2; a=23r++r
It is given that (r++r) = 338 pm 
a=23×338pm=6761.732=390.3pm

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An ionic solid A+B– crystallizes as a body centred cubic structure. The distance between cation and anion in the lattice is 338 pm. Calculate the edge length of the unit cell (in pm).