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An octahedral complex with molecular composition $M \cdot 5 {NH}_{3} \cdot Cl \cdot {SO}_{4}$ has two isomers, A and B. The solution of A gives a white precipitate with ${AgNO}_{3}$ solution and the solution of B gives white precipitate with ${BaCl}_{2}$ solution. The type of isomerism exhibited by the complex is:

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Ionisation isomerism

Linkage isomerism

Geometrical isomerism

Coordinate isomerism

answer is B.

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Detailed Solution

The complexes are $[\begin{matrix} M ({NH}_{3}) ({SO}_{4}) \\ (A) \end{matrix}] {Cl}^{-}$ and $[\begin{matrix} M ({NH}_{3}) Cl \\ (B) \end{matrix}] {SO}_{4}$ .These structures represent ionisation isomers and the phenomenon is ionisation isomerism.

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