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Q.

An organic compound A (C5H10O2)    reacts with Br2 in presence of phosphorous to produce B which can be resolved into enantiomers. B on dehydrobromination yields C(C5H8O2) which does not show stereoisomerism. C on decarboxylation gives an alkene which on further ozonolysis gives D and E. D gives Fehling’s test but E does not. The correct identity of these compounds are 

 

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a

A is (CH3)2CHCH2COOH

b

B is (CH3)2CHCHBrCOOH

c

C is (CH3)2C==CHCOOH  

d

E is acetone

answer is A, B, C, D.

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Dehydration products of carboxylic acids.

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