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Q.

An organic compound (C3H9N) (A), when treated with nitrous acid, gave a alcohol and N2 gas was evolved. (A) on warming with CHCI3 and caustic potash gave (C) which on reduction gave isopropylmethylamine. Predict the structure of (A).

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a

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b

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c

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d

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answer is A.

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Detailed Solution

On treating with nitrous acid, primary amine gives an alcohol and N2 gas. So, A should be primary amine.

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