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Q.

An organic compound contains C = 48% and H = 8%. Further 0.48 gm of the compound was

 kjeldalised and the liberated ammonia required 19.2 m mL N2H2SO4. The empirical formula of

the compound is  

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a

C4H8N2O

b

C6H8NO2

c

C5H9N2O

d

C4H10NO2

answer is A.

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Detailed Solution

% N = 1.4 × no of meq of H2SO4 used to neutralise NH3Mass of the compound

% N= 1.4 × 9.60.48 × = 28%

Element% of elementRelative numberof atomsSimplestratioC484812 = 44H881 = 88N282814 = 22O161616 = 11

Emperical formula is C4H8N2O

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