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Q.

An organic compound with molecular formula C7H8O dissolves in NaOH and gives characteristic colour with FeCl3. On treatment with Br2, it gives tribromo product  C7H5OBr3. The compound is 

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a

O-cresol

b

p-cresol

c

m-cresol

d

Anisol

answer is C.

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Detailed Solution

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Identification of Organic Compound

An organic compound with molecular formula C7H8O dissolves in NaOH and gives a characteristic colour with FeCl3. On treatment with Br2, it gives tribromo product C7H5OBr3. The compound is p-cresol (4-methylphenol).

This is because the compound is a phenol derivative which reacts with NaOH to form a phenolate ion (soluble in alkali) and gives violet colouration with FeCl3. The activated aromatic ring readily undergoes tribromination in presence of bromine, producing the tribromo derivative.

 

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