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Q.

An organic compound X gives a red precipitate on heating with Fehling’s solution. The reaction that yields X as major product is

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a

$HCHO \to_{(ii) H_{2} O}^{(i) {CH}_{3} Mgl}$

b

$C_{2} H_{5} Br + AgOH \overset{∆}{\to}$

c

$2 C_{2} H_{5} Br + {Ag}_{2} O \overset{∆}{\to}$

d

$C_{2} H_{2} + H_{2} O \to_{1 % H_{2} {SO}_{4}; 60^{o} C}^{40 % H_{2} {SO}_{4}}$

answer is D.

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Detailed Solution

The compound X gives a red precipitate on heating with Fehling's solution.
This indicates that the compound X is an aldehyde.
It can be obtained by the acid-catalyzed hydration of acetylene.

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