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Q.

An organic compound [A]C4H11N, shows optical activity and gives N2 gas on treatment with HNO2 . The compound  A reacts with PhSO2Cl producing a compound which is soluble in KOH . the structure of A is:

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a

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b

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c

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d

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answer is D.

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Detailed Solution

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Reaction 1: Diazotization Reaction

CH3CH2—CH—NH2
|
CH3
(A)
HNO3

CH3CH2—CH—OH
|
CH3
+
N2
 

Description: Primary amine (A) reacts with nitrous acid (HNO3) to form an alcohol and nitrogen gas (N2).

 

Reaction 2: Sulfonation Reaction

CH3CH2—CH—NH2
|
CH3
PhSO2Cl

H
|
CH3CH2—CH—N—S—Ph
|
CH3
O
||
O
(soluble in alkali)
 

Description: Primary amine reacts with benzenesulfonyl chloride (PhSO2Cl) to form N-alkylbenzenesulfonamide, which is soluble in alkali.

Note: Ph represents a phenyl group (C6H5)

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