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Q.

An organic compound C3H9 N (A), when treated with nitrous acid, gave alcohol and N2 gas was evolved. (A) on warming with CHCl3 and caustic potash gave (B) which on reduction gave diisopropylethylamine. Predict the structure of (A)

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a

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b

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c

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d

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answer is A.

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Detailed Solution

An organic compound C3H9 N(A), when treated with nitrous acid, gives primary amine. C3H9 N has two possible structures with -NH2

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Therefore, option A is correct.

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