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Q.

An tonic compound consists of only A+1 , B+2 and C-3 ions. Which of the following option(s) is/are correct w.r.t. their possible structure?

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a

Anions form cubic close packing and monovalent cations occupy all octahedral void and bivalent cations occupy half of tetrahedral void.

b

Bivalent cations form hexagonal close packing and monovalent cations occupy all octahedral voids and anions occupy half of tetrahedral voids.

c

Monovalent cations occupy alternate corners of a simple cube and bivalent cations occupy remaning alternate corners of the cube and anions occupy body centre of the cubs....

d

Bivalent cations form cubic close packing anions occupy all tetrahedral voids and monovalent cations occupy all octahedral voids.

answer is B.

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Detailed Solution

An ionic compound consists of only A+1 , B+2 and C-3 ions. In this case,

Anions form cubic close packing and monovalent cations occupy all octahedral void and bivalent cations occupy half of tetrahedral void. 

Bivalent cations form hexagonal close packing and monovalent cations occupy all octahedral voids and anions occupy half of tetrahedral voids. 

 

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