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Q.

An unknown compound (A) having molecular formula  C6H12O6 on acetylation gives acylated product whose molecular weight is 390. How many number of hydroxyl groups present in A?

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answer is 5.

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Detailed Solution

ROHROCOCH3 
Acylation of one hydroxyl group results in increment of  COCH2(or)  (C2H2O)
C6H12O6C6H12O6+(C2H2O)×5=C16H22O11   (Molecular weight = 390)
C6H12O6M.wt=180Difference wt.=390180=210
One  C2H2O having molecular weight  =42×5=210
No. of groups added = 5

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An unknown compound (A) having molecular formula  C6H12O6 on acetylation gives acylated product whose molecular weight is 390. How many number of hydroxyl groups present in A?