(A) ${\mathrm{N}}_2+2{\mathrm{O}}_2\iff 2{\mathrm{NO}}_2;{\mathrm{K}}_{\mathrm{c}}=2\times {10}^{-31}$

(B) $2\mathrm{NO}\iff {\mathrm{N}}_2+{\mathrm{O}}_2;{\mathrm{K}}_{\mathrm{c}}=2.2\times {10}^{-33}$

(C) $2{\mathrm{N}}_2{\mathrm{O}}_5\iff 2{ \mathrm{N}}_2+5{\mathrm{O}}_2;{\mathrm{K}}_{\mathrm{c}}=3.8\times {10}^{-32}$

(D) $2{\mathrm{N}}_2+{\mathrm{O}}_2\iff 2{ \mathrm{N}}_2\mathrm{O};{\mathrm{K}}_{\mathrm{c}}=4\times {10}^{-32}$

From the above data, the most stable oxide is

Since $N{O}_2$ has a lower value of the equilibrium constant, it will be the most stable nitrogen oxide. K1 is the stability constant The stability of oxide increases as the value of the equilibrium constant decreases. Other reactions have equilibrium constants with higher values. This makes these oxides less stable.

Therefore, the correct answer is option (A) $N{O}_2$.