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Q.

Analysis shows that nickel oxide has the formula Ni0.98O1.00.  The fractions of Ni2+ and Ni3+ ions in the crystal are  

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a

Ni2+=96%   &   Ni3+=4%

b

Ni2+=98%   &   Ni3+=2%

c

Ni2+=4%   &   Ni3+=96%

d

Ni2+=2%   &   Ni3+=98%

answer is D.

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Detailed Solution

 Ni0.98O1.00  have  98Ni  ions  &  100  O2  ions
Total cation charge = Total Anion charge
 2x+2943x=200x=94
 Ni+2  ions=94  and   Ni+3  ions=4Fraction  of   Ni+2=9498=0.96     %Ni+2=96%                            Ni+3=498=0.04     %Ni+3=4%
 

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