Q.

Anhydrous A𝑙C𝑙3 is covalent while A𝑙F3 is ionic. This is justified by

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a

Crystal structure

b

VB theory

c

Fajan's rules

d

Lattice energy

answer is C.

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Detailed Solution

According to Fajan’s rules, if the cation size is large and anion size is small, then the compound will have more ionic. Contrary if the cation size is small and the anion size is large, then compound should be a covalent.

In anhydrous AlCl3, , the anion Cl-has large size hence it can polarize easily and forms covalent bond with Al+3. But in the case of AlF3 the anion F− size is small. Therefore, F− ion reacts with Al+3 to form ionic bond.

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