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Q.

Anhydrous AlCl3 is covalent while AlF3 is ionic. This is justified by

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a

Crystal structure

b

VB theory

c

Fajan's rules

d

Lattice energy

answer is C.

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Detailed Solution

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Fajan's rules explains the covalent character. based on the following factors:

  • Small sized cation and large sized anion favours the formation of covalent bond.
  • More charge on cation and anion favours the formation of covalent bond.

Hence AlCl3 is covalent while AlF3 is ionic.

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Anhydrous AlCl3 is covalent while AlF3 is ionic. This is justified by