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Q.

Anhydrous aluminium chloride $({Al}_{2} {Cl}_{6})$ is covalent compound and soluble in water giving:

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a

${[{AlCl}_{2} {(H_{2} O)}_{4}]}^{+} and {[{AlCl}_{4} {(H_{2} O)}_{2}]}^{-} ions$

b

${Al}^{3 +} and {Cl}^{-} ions$

c

none of the above

d

${[Al {(H_{2} O)}_{6}]}^{3 +} and {Cl}^{-} ions$

answer is C.

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Detailed Solution

${AlCl}_{3} \cdot 6 H_{2} O \overset{dissociation}{⟶} {[{AlCl}_{2} {(H_{2} O)}_{4}]}^{+} + {[{AlCl}_{4} {(H_{2} O)}_{2}]}^{-}$

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Anhydrous aluminium chloride Al2Cl6 is covalent compound and soluble in water giving: