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Q.

Anhydrous AlCl3 is covalent. From the data given below
Lattice energy =5137KJ/mol.

ΔH hydration for  Al3+=4665KJ/mol

ΔH hydration for  Cl=381KJ/mol

Identify the correct statement.

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a

The solution will consist of hydrated Al3+ and Cl

b

None of the above

c

It will remain covalent in aqueous solution
 

d

The solution will consists of  Al3+ and Cl

answer is C.

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Detailed Solution

AlCl3 (Anhydrous) AlCl3(aq)

ΔH of reaction= Energy released during hydration + Energy used during ionization

4665(3×381)+5137=671

Thus AlCl3 would become ionic in aqueous solution as the formation of ions will take place because

ΔHhydration >ΔHionization 

Hence the correct option is c.

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