Q.

Aniline behaves as a weak base. When 0.1 M, 50 mL solution of aniline was mixed with 0.1 M, 25 mL solution of HCl the pH of resulting solution was 8. Then the pH of 0.01 M solution of anilinism chloride will be Kw=1014:

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a

6.5

b

5.5

c

6

d

5

answer is C.

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Detailed Solution

148=pKb+log2.52.5 pKb=6

pH=12pKwpKblogc=12[146log0.01]

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