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Aniline gives meta derivative as major product with

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a
CH3COCl/pyridine
b
HNO3+H2SO4
c
Br2/water
d
CH3Cl/pyridine

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detailed solution

Correct option is B

Nitration is carried out in an acidic medium. In a strongly acidic medium, aniline is protonated to give anilinium ion (which is meta-directing). For this reason, aniline on nitration gives a substantial amount of m-nitroaniline.

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