Aniline gives meta derivative as major product with

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HNO₃+H₂SO₄

CH₃COCl/pyridine

CH₃Cl/pyridine

Br₂/water

answer is B.

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Detailed Solution

Nitration is carried out in an acidic medium. In a strongly acidic medium, aniline is protonated to give anilinium ion (which is meta-directing). For this reason, aniline on nitration gives a substantial amount of m-nitroaniline.

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