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Aniline gives meta derivative as major product with

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An Intiative by Sri Chaitanya

a

$C H_{3} C O C l$ /pyridine

b

$H N O_{3}$ + $H_{2} S O_{4}$

c

$B r_{2}$ /water

d

$C H_{3} C l$ /pyridine

answer is B.

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Detailed Solution

Aniline is an electron donating group, hence it is a ortho/para directing group
Aniline is a weak base. Under acidic medium aniline gets protonated and converted to anilinium ion.
Anilinium ion does not have free lone pair of electron, so ortho/para positions on the benzene nucleus become electron deficient Anilinium ion becomes meta directing group .

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Aniline gives meta derivative as major product with