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Q.

Aniline is less basic than

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a

${NH}_{3}$

b

${CH}_{3} {NH}_{2}$

c

N-Methyl aniline

d

All the above

answer is D.

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Detailed Solution

The lone pair of electrons present on nitrogen of aniline participate in conjugation with benzene nucleus hence it is weak base
In ammonia lone pair of electrons present on nitrogen are free hence it is more basic than aniline
In methylamine due to +I effect of methyl group, increases electron density on nitrogen. Hence it is more basic than aniline
Even though in N-Methyl aniline lone pair of electrons participate in conjugation it is more basic than aniline due to +I effect of methyl group which increases electron density on nitrogen of N-Methyl aniline

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