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Q.

Aniline when heated with NaNO2 and HCl at 050C the product formed is

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a

benzene diazonium chloride

b

dichloro benzene

c

chloro benzene

d

chloro aniline

answer is B.

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Detailed Solution

Aniline Diazotization Reaction

Diazotization of Aniline

Aniline is heated with sodium nitrite (NaNO2) and hydrochloric acid (HCl) at 0–5°C.

Reaction:

C6H5NH2 + NaNO2 + 2HCl → C6H5N2Cl + 2H2O + NaCl

Product Formed:

Benzene diazonium chloride (C6H5N2Cl)

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