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Q.

Aqueous sodium chloride solution is electrolyzed under cold conditions to produce sodium hypochlorite, which is obtained by disproportionation of all released Cl2 in NaOH solution thoroughly. How many days will an electrolytic cell operate to produce 10 L of 7.45% (by mass–volume) solution of NaClO if the cell current is 2.5 A? Report the value to nearest integer.

1 F = 96500 C; Atomic weights: Na = 23, Cl = 35.5, O = 16

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answer is 9.

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Detailed Solution

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2NaCl+2H2Oelectrolysis2NaOH+H2+Cl2 2NaOH+Cl2NaCl+NaClO+H2O

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Aqueous sodium chloride solution is electrolyzed under cold conditions to produce sodium hypochlorite, which is obtained by disproportionation of all released Cl2 in NaOH solution thoroughly. How many days will an electrolytic cell operate to produce 10 L of 7.45% (by mass–volume) solution of NaClO if the cell current is 2.5 A? Report the value to nearest integer.1 F = 96500 C; Atomic weights: Na = 23, Cl = 35.5, O = 16