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Q.

Aqueous solution of ortho-boric acid can be titrated against sodium hydroxide using phenolphthalein indicator only in presence of

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a

trans-glycerol

b

cis-glycerol

c

 Both (2) and (3) 

d

Catechol

answer is D.

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Detailed Solution

Titration of aqueous solution of boric acid against NaOH is done using phenolphthalein in the presence of polyhydroxy compounds named as catechol and cis-glycerol. Boric acid forms a stable complexes with polyhydroxy compounds which helps in releasing H+ and H3O+ in the solution This enhances the acidic strength of boric acid and then, it is titrated against NaOH.

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