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Q.

Aqueous solution of CuCl2  is subjected to electrolysis using Pt electrodes. Then the correct statement is

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a

pH  progressively increases

b

pHprogressively decreases

c

Cannot be predicted

d

pHremains unaffected

answer is A.

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Detailed Solution

AqCuCl2  isasalt  of  SAWB.It's  pH<7

On electrolysis  At Cathode
                              Discharge potential of Cu+2is  less  than  H2O

  Cu+2+2eCu
            At Anode
                       Discharge potential of  Clis  lessthan  H2O
2ClCl2+2eThe  left  over  solution  will  be  H2Owith  pH=7pH<7  changesto  PH=7pH   progressively  increases

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