Q.

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Arrange above phenol in increasing order of pKa value:

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a

I < III < II

b

III < I < II

c

III < II < I

d

I < II < III

answer is C.

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Detailed Solution

Ka  order  in:  I  <  II  <  III;                pKa  order:  III  <  II  <  I

Presence of   electron withdrawing group at -ortho and -para positions increases the acidic nature of phenols.

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